Preparation of Oily Sludge-Derived Activated Carbon and Its Adsorption Performance for Tetracycline Hydrochloride.

Oily sludge-derived activated carbon was prepared using the potassium hydroxide (KOH) activation method using oily sludge as a raw material, and one-factor experiments determined the best conditions for preparing activated carbon. The activated carbon's morphological structure and surface chemical properties were analyzed by scanning different characterization tools, and the adsorption behavior of tetracycline hydrochloride was investigated. The results showed that the optimum conditions for preparing oily sludge-derived activated carbon were an activation temperature of 400 °C, activation time of 30 min, activator concentration of 1 mol/L, and impregnation ratio of 2 mL/g. After activation, the activated carbon had more pores and a more orderly crystal structure arrangement, the specific surface area was 2.07 times higher than that before activation, and the surface was rich in functional groups such as -HO, -C-O, -C=C, and -C-H, which increased the active sites of activated carbon. Physicochemical effects dominated the adsorption process. It belonged to the spontaneous heat absorption process under the quasi-secondary kinetic and Langmuir isothermal models. The maximum monolayer adsorption capacity of KOH-activated carbon was 205.1 mg·g-1.

The Influence of Halide Ion Substitution on Energy Structure and Luminescence Efficiency in CeBr2I and CeBrI2 Crystals.

This study aims to determine the optimum composition of the CeBr1-xIx compound to achieve the maximum light output. It is based on calculations of the band energy structure of crystals, specifically taking into account the characteristics of the mutual location of local and band 5d states of the Ce3+ ions. The band energy structures for CeBr2I and CeBrI2 crystals were calculated using the projector augmented wave method. The valence band was found to be formed by the hybridized states of 4p Br and 5p I. The 4f states of Ce3+ are located in the energy forbidden band gap. The conduction band is formed by the localized 5d1 states, which are created by the interaction between the 5d states of Ce3+ and the 4f0 hole of the cerium ion. The higher-lying delocalized 5d2 states of Ce3+ correspond to the energy levels of the 5d states of Ce3+ in the field of the halide Cl0 (Br0) hole. The relative location of 5d1 and 5d2 bands determines the intensity of 5d-4f luminescence. The bottom of the conduction band is formed by localized 5d1 states in the CeBr2I crystal. The local character of the bottom of the conduction band in the CeBr2I crystal favors the formation of self-trapped Frenkel excitons. Transitions between the 5d1 and 4f states are responsible for 5d-4f exciton luminescence. In the CeBrI2 crystal, the conduction band is formed by mixing the localized 5d1 and delocalized 5d2 states, which leads to quenching the 5d-4f luminescence and a decrease in the light output despite the decrease in the forbidden band gap. CsBr2I is the optimum composition of the system to achieve the maximum light output.

Research on the Durability and Reliability of Industrial Layered Coatings on Metal Substrate Due to Abrasive Wear.

This paper discusses the issue of evaluating the durability and reliability of organic coatings applied on the outer surfaces of roofing sheets. Two sheets, i.e., ZA200 and S220GD, were selected as research objects. Metal surfaces of these sheets are protected with multilayer organic coatings to protect them against weather conditions, assembly, and operational damages. The durability of these coatings was tested by evaluating their resistance to tribological wear using the ball-on-disc method. The testing was conducted in reversible gear according to a sinuous trajectory at a 3 Hz frequency. The test load was 5 N. When the coating was scratched, the metallic counter sample touched the metallic surface of the roofing sheet, which indicated a significant drop in electrical resistance. It is assumed that the number of performed cycles specifies the durability of the coating. Weibull analysis was applied to examine the findings. The reliability of the tested coatings was evaluated. The tests have confirmed that the structure of the coating is essential for the durability and reliability of products. The research and analysis included in this paper present important findings.

Effect of Hydrothermal Factors on the Microhardness of Bulk-Fill and Nanohybrid Composites.

This study evaluates the effect of aging in artificial saliva and thermal shocks on the microhardness of the bulk-fill composite compared to the nanohybrid composite. Two commercial composites, Filtek Z550 (3M ESPE) (Z550) and Filtek Bulk-Fill (3M ESPE) (B-F), were tested. The samples were exposed to artificial saliva (AS) for one month (control group). Then, 50% of the samples from each composite were subjected to thermal cycling (temperature range: 5-55 °C, cycle time: 30 s, number of cycles: 10,000) and another 50% were put back into the laboratory incubator for another 25 months of aging in artificial saliva. The samples' microhardness was measured using the Knoop method after each stage of conditioning (after 1 month, after 10,000 thermocycles, after another 25 months of aging). The two composites in the control group differed considerably in hardness (HK = 89 for Z550, HK = 61 for B-F). After thermocycling, the microhardness decrease was for Z550 approximately 22-24% and for B-F approximately 12-15%. Hardness after 26 months of aging decreased for Z550 (approximately 3-5%) and B-F (15-17%). B-F had a significantly lower initial hardness than Z550, but it showed an approximately 10% lower relative reduction in hardness.

Comparative Evaluation of the Tribological Properties of Polymer Materials with Similar Shore Hardness Working in Metal-Polymer Friction Systems.

This article presents comparative tests of contact strength and tribological wear resistance of polymer sliding materials of the polyamide group. The aim of this work was to study Shore hardness, indentation hardness, modulus, creep, relaxation, Martens hardness and sliding wear resistance of two commercial materials. One of these materials was produced with the recycling process in mind. Abrasion tests were performed against a stainless-steel ball (100CRr6) on a normal load of 5 N for 23,830 friction cycles. The samples were tested under dry friction conditions and taking into account the hydrothermal factor, the presence of which was assumed in the anticipated operating conditions. It was distilled water at a temperature of 50 °C. The volumetric wear of the samples under various environmental conditions was assessed and related to the mechanical properties, in particular, Shore hardness. This mechanical size, which characterizes the surface, was considered the most frequently used by engineers selecting polymeric materials for tribological applications in industry. The Shore hardness of both materials was similar, which may indicate similar tribological performance properties. However, research and analysis indicate the need to use measures that directly correspond to tribological wear. The friction and wear of both materials varied. The coefficient of friction in hydrothermal conditions was lower and the wear was higher than in the dry friction test. It seems that it was not hardness that determined the suitability in the anticipated operating conditions, but the ability to form a sliding layer on the friction surface. The properties of the material that has been envisaged as a replacement may be appropriate for the intended uses.

Computer Modelling of Energy Structure of Yb3+ and Lu3+ Doped LaF3 Crystals.

The energy band structure, as well as partial and total densities of states have been calculated for LaF3:Yb and LaF3:Lu crystals within density functional theory using the projector augmented wave method and Hubbard corrections (DFT + U). The influence of geometric optimization on the results of energy band calculations of LaF3:Ln crystals (Ln = Yb, Lu) was analysed and the absence of relaxation procedure is confirmed to negatively influence the energy position of states, and the variability between obtained results of different optimization algorithms are within the calculation accuracy. The top of the valence band of LaF3 is confirmed to be formed by the 2pF--states and the bottom of the conduction band is formed by the 5d-states of La3+. The positions of the 4f-states and 5d-states of activator ions in LaF3 were studied. It is shown that the 4f-states of Yb3+ are slightly above the top of the valence band and the 4f-states of Lu3+ to be 3.5 eV below the top of the valence band. The energy levels of the 5d states of the impurities are energetically close to the bottom of the LaF3 conduction band. The calculated band gap of 9.6 eV for LaF3 is in a good agreement with the experimental result and is not affected by impurity ions.

Individualized Short-Term Electric Load Forecasting Using Data-Driven Meta-Heuristic Method Based on LSTM Network.

Short-term load forecasting is viewed as one promising technology for demand prediction under the most critical inputs for the promising arrangement of power plant units. Thus, it is imperative to present new incentive methods to motivate such power system operations for electricity management. This paper proposes an approach for short-term electric load forecasting using long short-term memory networks and an improved sine cosine algorithm called MetaREC. First, using long short-term memory networks for a special kind of recurrent neural network, the dispatching commands have the characteristics of storing and transmitting both long-term and short-term memories. Next, four important parameters are determined using the sine cosine algorithm base on a logistic chaos operator and multilevel modulation factor to overcome the inaccuracy of long short-term memory networks prediction, in terms of the manual selection of parameter values. Moreover, the performance of the MetaREC method outperforms others with regard to convergence accuracy and convergence speed on a variety of test functions. Finally, our analysis is extended to the scenario of the MetaREC_long short-term memory with back propagation neural network, long short-term memory networks with default parameters, long short-term memory networks with the conventional sine-cosine algorithm, and long short-term memory networks with whale optimization for power load forecasting on a real electric load dataset. Simulation results demonstrate that the multiple forecasts with MetaREC_long short-term memory can effectively incentivize the high accuracy and stability for short-term power load forecasting.

Development and Experimental Research of Different Mechanical Designs of an Optical Linear Encoder's Reading Head.

Optical linear encoders are widely used in manufacturing. They are accurate and have a relatively high resolution and good repeatability. However, there are a lot of side effects, which have an inevitable impact on the performance of an encoder. In general, the majority of these effects could be minimized by the appropriate design of an encoder's reading head. This paper discusses the working principle of and commonly occurring errors in optical linear encoders. Three different mechanical designs are developed and implemented in the experimental reading head of the linear encoder in order to evaluate how mechanical construction influences the displacement measurement accuracy and total performance of the encoder.

Quality Evaluation of Selected Organic Coatings Used on Roofing Sheets.

This paper discusses the aspects of quality evaluation of organic coatings on roofing sheet surfaces. Scratch resistance was defined as a quality property of an industrial product. The research was comparative and exploratory in terms of the method applied and research results. The study followed a quantitative and qualitative approach in which evaluation is based on several parameters, such as the mechanical behavior of a coating in a scratch test, profile and depth of remained damage, and microscopic evaluation of damage mechanisms. The study parametrically describes coating damage and destruction mechanisms. It has been shown that the resistance of the coatings is not identical, and the research results confirm that the applied approach is relevant to evaluate qualitative features of roofing sheet metal coatings.

Reliability Analysis for Unrepairable Automotive Components.

The analysis of the reliability parameters of a technical object and the determination of the change in the reliability of the object over time, requires the knowledge of the functional characteristics and reliability parameters of the elements included in a system. On the basis of the failure data of the selected element of the object, in this case the vehicle, it is possible to determine the average working time to failure of the element and the appropriate form of distribution that characterizes the reliability and durability parameters of the tested element. The main purpose of the research presented in the article was to develop a method of assessing the reliability of an electronic component of a vehicle-a boot lid contactor. This paper also presents three possible methods of repairing the boot lid contactor (sealing the housing with adhesive with better way, replacing the element with a new one or the most time-consuming solution, changing the shape of the boot lid). The authors also decided to determine the reliability and cost parameters that will allow preventive replacement of this element. The tests were carried out on a fleet of 61 vehicles of the same model, but with different body structures. Contactor failures were reported in 41 cases, of which 29 were in the hatchback construction and 12 in the estate type. The analysis of the distribution selection for the tested part of the passenger car-the boot lid contactor-was performed using the Likelihood Value (LKV) test to determine the rank of distributions. Also the maximum likelihood (MLE) method was used to estimate the distribution parameters. The three-parameter Weibull distribution was the best-fitted distribution in both cases. It was clearly defined that one model of car with two different types of body have vastly different reliability characteristic. Based on the reliability characteristic and parameters, the appropriate preventive actions can be taken, minimizing the risk of damage, thus avoiding financial losses and guaranteeing an appropriate level of vehicle safety.

Effect of Artificial Aging on Mechanical and Tribological Properties of CAD/CAM Composite Materials Used in Dentistry.

With easy-to-process 3D printing materials and fast production, the quality of dental services can be improved. In the conventional procedure, the dentist makes temporary crowns directly in the patient's mouth, e.g., from the most commonly used bis-acrylic composites. Temporary crowns made directly in the office without the use of CAD/CAM are often of inferior quality, which directly results in impaired hygiene, poorer masticatory mechanics, greater deposition of plaque, calculus and sediment, and may adversely affect periodontal and gum health. The mechanical strength, resistance to aging and abrasion of 3D printing materials are higher than those of the soft materials used in conventional methods. This translates into durability. The patient leaves the surgery with a restoration of higher utility quality compared to the conventional method. The objective of the paper was to determine the influence of aging in artificial saliva of AM (additive manufacturing) orthodontic composites on their functional properties. For the purpose of the study, fillings well-known worldwide were selected. These were traditional UV-curable resins (M I, M II, M III, M V) and a hybrid material based on a UV-curable resin (M VI). Samples were stored in artificial saliva at 37 ± 1 °C in a thermal chamber for 6 months. Indentation hardness, frictional tests and sliding wear measurements were conducted. A comparison between various materials was made. Descriptive statistics, degradation coefficients, H2E, Archard wear and specific wear rate were calculated. The Weibull statistical test for indentation hardness was performed and Hertzian contact stresses for the frictional association were calculated for unaged (M I, M II, M III, M V, M VI) and aged (M I AS, M II AS, M III AS, M V AS, M VI AS) samples. M I exhibited the lowest average hardness among the unaged materials, while M III AS had the lowest average hardness among the aged materials. Comparably low hardness was demonstrated by the M I AS material. The coefficient of friction values for the aged samples were found to be higher. The lowest wear value was demonstrated by the M I material. The wear resistance of most of the tested materials deteriorated after aging. The M VI AS material had the highest increase in wear. According to the results provided, not only the chemical composition and structure, but also aging have a great impact on the indentation hardness and wear resistance of the tested orthodontic materials.

Analysis of the Statistical Comparability of the Hardness and Wear of Polymeric Materials for Orthodontic Applications.

BACKGROUND: Clinical success depends on the contact strength and wear resistance of medical devices made of polymer materials. The scientific goal resulted from the problem of using different methods of surface evaluation of materials used in the production of orthodontic appliances. The purpose of the work was an experimental comparative assessment of indentation hardness and scratch hardness and the sliding wear of four selected polymeric materials used in the manufacture of orthodontic appliances. METHODS: Four commercial materials were compared. Shore hardness tests and a scratch test with a Rockwell indenter were performed. A sliding wear test was performed using the ball-on-disc method. Statistical PCA and correlation analyses were performed. RESULTS: The results of scratch hardness measurements using a contact profilometer correlated with the Shore hardness to a greater extent than measurements made using an optical microscope. PCA showed that Shore hardness explains 45% of the total variance in all the results across the materials. CONCLUSIONS: The scratch hardness method allows for a more explicit ranking of orthodontic polymeric materials when measurements are made with a profilometer. The ranking of sliding wear resistance should be made separately.

Influence of Thermal Shocks on Residual Static Strength, Impact Strength and Elasticity of Polymer-Composite Materials Used in Firefighting Helmets.

The article presents results of experimental studies on mechanical properties of the polymer-composite material used in manufacturing firefighting helmets. Conducted studies included static and impact strength tests, as well as a shock absorption test of glass fiber-reinforced polyamide 66 (PA66) samples and firefighting helmets. Samples were subject to the impact of thermal shocks before or during being placed under a mechanical load. A significant influence of thermal shocks on mechanical properties of glass fiber-reinforced PA66 was shown. The decrease in strength and elastic properties after cyclic heat shocks ranged from a few to several dozen percent. The average bending strength and modulus during the 170 degree Celsius shock dropped to several dozen percent from the room temperature strength. Under these thermal conditions, the impact strength was lost, and the lateral deflection of the helmet shells increased by approximately 300%. Moreover, while forcing a thermal shock occurring during the heat load, it was noticed that the character of a composite damage changes from the elasto-brittle type into the elasto-plastic one. It was also proved that changes in mechanical and elastic properties of the material used in a helmet shell can affect the protective abilities of a helmet.

Mechanical Properties and Strength Reliability of Impregnated Wood after High Temperature Conditions.

The paper presents the results of the research into the impact of impregnation of wood on its bending strength and elastic modulus under normal conditions and after thermal treatment and investigates its structural reliability. Pinewood, non-impregnated and pressure impregnated with a solution with SiO2 nanoparticles, was used in this research. The use of nanoparticles decreases the flammability of timber among others. Some of the tested samples were treated at 250 °C. This temperature corresponds to the boundary of the self-ignition of wood. This elevated temperature was assumed to be reached by a given speed of heating within 10 min, and then the samples were stored in these conditions for 10 and 20 min. The tests demonstrate that the bending strength of the impregnated wood was slightly improved, the impregnation did not impact the elastic modulus of the material in all such conditions, and the residual strength decreased less for the wood impregnated after being exposed to the elevated temperatures. The reliability analysis proves a positive effect of impregnation with a solution with SiO2 on the durability of wood, both after being exposed to normal and elevated temperatures. The distribution of the failure rates indicates a more intensive degradation of non-impregnated wood. The distribution of the survival function demonstrates a more probable non-destruction of impregnated wood after elevated temperature conditions.

Bending Behaviour of Polymeric Materials Used on Biomechanics Orthodontic Appliances.

This paper discusses the issues of strength and creep of polymeric materials used in orthodontic appliances. Orthodontic biomechanics is focused on the movement of individual teeth or dental groups as a result of the force applied by orthodontic appliances. Stresses in the construction of functional and biomechanical appliances is generated when using the apparatus in the oral cavity. The orthodontic appliance must maintain its shape and not be damaged during treatment so strength and creep resistance are fundamental properties. It was assumed that the clinical success of orthodontic appliances can be determined by these performance properties. The aim of the work was the experimental assessment of comparative bending strength and creep resistance of selected popular polymer materials used in the production of biomechanical orthodontic appliances. Four commercial materials manufactured by the world class producers were tested: NextDent Ortho Rigid (Vertex-Dental B.V., Soesterberg, The Netherlands) marked as "1A"; Erkocryl (ERKODENT Erich Kopp GmbH, Pfalzgrafenweiler, Germany)-"2A"; Vertex Orthoplast (Vertex Dental B.V.), blue, marked as "3A" and material with the same name as "3A" but orange, marked in the article as "4A". All the tests were carried out after aging in artificial saliva for 48 h at a temperature of 37 °C. Flexular strength and flexular modulus were made using the three point bending method according to the ISO 178 technical standard. Creep tests were carried out according to the method contained in ISO 899-2. The creep test was carried out in an artificial saliva bath at 37 °C. The creep tests showed significant differences in the strength, modulus and deformability of the tested materials. The strength reliability of the tested materials also varied. The research shows that the 2A material can be used for orthodontic applications in which long-term stresses should be lower than 20 MPa.

A Software Deep Packet Inspection System for Network Traffic Analysis and Anomaly Detection.

In this paper, to solve the problem of detecting network anomalies, a method of forming a set of informative features formalizing the normal and anomalous behavior of the system on the basis of evaluating the Hurst (H) parameter of the network traffic has been proposed. Criteria to detect and prevent various types of network anomalies using the Three Sigma Rule and Hurst parameter have been defined. A rescaled range (RS) method to evaluate the Hurst parameter has been chosen. The practical value of the proposed method is conditioned by a set of the following factors: low time spent on calculations, short time required for monitoring, the possibility of self-training, as well as the possibility of observing a wide range of traffic types. For new DPI (Deep Packet Inspection) system implementation, algorithms for analyzing and captured traffic with protocol detection and determining statistical load parameters have been developed. In addition, algorithms that are responsible for flow regulation to ensure the QoS (Quality of Services) based on the conducted static analysis of flows and the proposed method of detection of anomalies using the parameter Hurst have been developed. We compared the proposed software DPI system with the existing SolarWinds Deep Packet Inspection for the possibility of network traffic anomaly detection and prevention. The created software components of the proposed DPI system increase the efficiency of using standard intrusion detection and prevention systems by identifying and taking into account new non-standard factors and dependencies. The use of the developed system in the IoT communication infrastructure will increase the level of information security and significantly reduce the risks of its loss.

Hardness and Wear Resistance of Dental Biomedical Nanomaterials in a Humid Environment with Non-Stationary Temperatures.

This study discusses a quantitative fatigue evaluation of polymer-ceramic composites for dental restorations, i.e., commercial material (Filtek Z550) and experimental materials Ex-nano (G), Ex-flow (G). Their evaluation is based on the following descriptors: microhardness, scratch resistance, and sliding wear. In order to reflect factors of environmental degradation conditions, thermal fatigue was simulated with a special computer-controlled device performing algorithms of thermocycling. Specimens intended for the surface strength and wear tests underwent 104 hydrothermal fatigue cycles. Thermocycling was preceded by aging, which meant immersing the specimens in artificial saliva at 37 °C for 30 days. Microhardness tests were performed with the Vickers hardness test method. The scratch test was done with a Rockwell diamond cone indenter. Sliding ball-on-disc friction tests were performed against an alumina ball in the presence of artificial saliva. A direct positive correlation was found between thermocycling fatigue and microhardness. The dominant mechanism of the wear of the experimental composites after thermocycling is the removal of fragments of the materials in the form of flakes from the friction surface (spalling). Hydrothermal fatigue is synergistic with mechanical fatigue.

Hydro-Thermal Fatigue of Polymer Matrix Composite Biomaterials.

This study discusses a quantitative fatigue evaluation of polymer-ceramic composites for dental restorations, i.e., commercial (Filtek Z550) and experimental Ex-nano (G), Ex-flow (G). Their evaluation is based on the following descriptors: mechanical strength, elastic modulus and strain work to fracture. Supposed to reflect factors of environmental degradation conditions, thermal fatigue was simulated with a special computer-controlled device performing algorithms of thermocycling. The specimens intended for the strength test underwent 104 hydro-thermal fatigue cycles. This procedure of thermocycling was preceded by aging, which meant immersing the specimens in artificial saliva at 37 °C for 30 days. The strength tests after aging only and after aging and thermocycles were performed in line with the three-point flexural strength (TFS) test, specified in ISO 4049, and the biaxial flexural strength (BFS) test, specifically piston-on-three-ball in accordance with ISO 6872. Based on the results, it can be stated that composites with higher volume content of inorganic particles after aging only show higher strength than materials with lower filler particle content. For example, the average flexural bending strength of the Ex-flow (G) composite was about 45% lower than the value obtained for the Ex-nano (G) material. The residual strength after thermocycles is significantly lower for the experimental composites, whereas a smaller decrease in strength is recorded for the commercial composites. Decreases in strength were about 4% (Filtek Z550), 43% (Ex-nano (G)), and 29% (Ex-flow (G)) for the BFS test; and about 17% (Filtek Z550), 55% (Ex-nano (G)), 60% (Ex-flow (G)) for the TFS test. The elastic modulus of the experimental composites after only aging is higher (about 42%) than that of the commercial composite, but the elastic modulus of the commercial composite increases significantly after thermocycling. A descriptor known as strain work to fracture turns out to be a good descriptor for evaluating the hydro-thermal fatigue of the tested polymer-ceramic composites.

The Effect of Thermocycling on Surface Layer Properties of Light Cured Polymer Matrix Ceramic Composites (PMCCs) Used in Sliding Friction Pair.

This paper discusses the problem of thermocycling effect of light-curing polymer-ceramic composites. Cyclic thermal shocks were simulated in laboratory conditions. As a rule, these loads were supposed to reproduce the actual conditions of biomaterials exploitation. Periodically variable stresses occurring in dental restorations are associated with the wear of cold and hot foods and beverages. They lead to changes in the properties of composites, including the properties of the surface layer. The aim of the work was to assess the impact of cyclic hydrothermal interactions on the properties of the surface layer of composites relevant to the operational quality. Two commercial materials manufactured by the world's leading producer (3M ESPE)-Filtek Z550, Filtek Flow and two experimental, micro-hybrid and flow type composites marked Ex-mhyb(P) and Ex-flow(P), respectively. All tests were carried out before and after hydro-thermal cycles (flowing water thermocycling). Micro-hardness test using the Vickers method, indentation hardness, and resistance to tribological wear in a ball-disc system in sliding friction conditions were performed. In addition, observations of the surface layer of composites on the SEM (scanning electron microscope) were carried out. It was noticed that semi-liquid composites, containing a smaller amount of filler, retain higher stability of mechanical and tribological properties of the surface layer under cyclic hydro-thermal loads. Coefficient of friction of samples after hydro-thermal cycles increased for micro-hybrid materials and Filtek Flow (FFlow) composite. In the case of Ex-flow(P) material, the coefficient of friction decreased. The microhardness of composites also changed, the variability of this size depended on the type of material. Composites with a higher content of filler particles were characterized by greater variability of microhardness under the influence of thermocycles. The resistance to tribological wear also changed in a similar way. Composites containing higher volume fraction of inorganic filler showed higher tribological wear after thermocycling. The wear resistance of flow composites changed to a lesser extent, after thermocycling increased. The paper also showed that, in real kinematic nodes, the surface layer of light-curing ceramic-polymer composites is exposed to significant non-tribological (erosive, thermal, and chemical) defects that synergize with tribological ones. In slip pairs loaded dynamically, under mixed friction conditions, tribological wear of PMCCs (polymer matrix ceramic composites) is manifested by spalling (spalling of the material flakes, in particular the polymer phase) and pitting (crushing wear caused by wear products, in particular large filler particles or clusters, previously adhesively extracted).